Products

Polybutadiene Rubber

    • Product Name: Polybutadiene Rubber
    • Chemical Name (IUPAC): poly(1,3-butadiene)
    • CAS No.: 9003-17-2
    • Chemical Formula: (C4H6)n
    • Form/Physical State: Solid/Rubber Sheets
    • Factroy Site: Yushan Island, Gaoting Town, Daishan County, Zhoushan City, Zhejiang Province
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Zhejiang Petroleum & Chemical Co., Ltd.
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    Specifications

    HS Code

    337947

    Chemical Formula (C4H6)n
    Appearance Translucent or white solid
    Density 0.90-0.92 g/cm3
    Glass Transition Temperature -100°C to -85°C
    Molecular Weight High, varies depending on polymerization
    Tensile Strength 10-18 MPa
    Elongation At Break 300-500%
    Hardness Shore A 30-70
    Rebound Resilience 70-80%
    Abrasion Resistance Excellent
    Thermal Conductivity 0.17 W/m·K
    Solubility In Water Insoluble
    Vulcanization Yes, commonly used with sulfur

    As an accredited Polybutadiene Rubber factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Polybutadiene Rubber is typically packaged in 25 kg bags, sealed for protection against moisture, and labeled with product and safety information.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Polybutadiene Rubber typically holds about 18-20 metric tons, packed in palletized bales or bags for shipping.
    Shipping Polybutadiene Rubber is shipped as solid blocks, bales, or granules, typically packaged in polyethylene-lined paper bags or bulk containers to prevent contamination. Keep containers tightly sealed, store in a cool, dry, well-ventilated area, and protect from direct sunlight and sources of ignition. Ensure compliance with applicable regulations during shipping.
    Storage Polybutadiene rubber should be stored in a cool, dry, and well-ventilated area, away from direct sunlight, heat sources, and ignition points. Keep containers tightly closed to avoid contamination and degradation. Protect from contact with strong oxidizers and avoid exposure to moisture. Store at temperatures below 30°C and follow all relevant safety guidelines specific to polymer and rubber materials.
    Shelf Life Polybutadiene rubber typically has a shelf life of about 5 years when stored in cool, dry conditions away from sunlight.
    Application of Polybutadiene Rubber

    Tensile Strength: Polybutadiene Rubber with high tensile strength is used in tire manufacturing, where it ensures enhanced resistance to wear and extended tread life.

    Molecular Weight: Polybutadiene Rubber of medium molecular weight is used in golf ball cores, where it provides optimal energy transfer and improved resilience.

    Cis-Content: Polybutadiene Rubber with high cis-content is used in vibration isolators, where it delivers superior flexibility and dynamic damping properties.

    Glass Transition Temperature: Polybutadiene Rubber with low glass transition temperature is used in winter tire compounds, where it maintains elasticity and grip in subzero conditions.

    Impurity Level: Polybutadiene Rubber with low impurity level is used in pharmaceutical stoppers, where it guarantees chemical purity and minimizes contamination risk.

    Particle Size: Polybutadiene Rubber with fine particle size is used in rubber modification for plastics, where it enables uniform dispersion and improved impact resistance.

    Stabilizer Content: Polybutadiene Rubber with optimized stabilizer content is used in conveyor belts, where it enhances oxidative stability and prolongs operational life.

    Viscosity: Polybutadiene Rubber with controlled viscosity is used in adhesives, where it ensures processability and consistent bonding performance.

    Melting Point: Polybutadiene Rubber with tailored melting point is used in hot melt processing, where it allows efficient molding and smooth surface finishing.

    Aging Resistance: Polybutadiene Rubber with enhanced aging resistance is used in automotive gaskets, where it prevents degradation and preserves sealing performance over time.

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    Certification & Compliance
    More Introduction

    Polybutadiene Rubber: Practical Choices from the Factory Floor

    Real Uses and Daily Demands for Polybutadiene Rubber

    From where we stand at the production lines, Polybutadiene Rubber is not just another synthetic rubber. It keeps factories moving across the tire, plastic, and footwear sectors, and we measure its value in the thousands of tons running through our reactors every month. While paper descriptions can look technical, we see the impact of batch-to-batch consistency, raw material sourcing, and small choices in catalyst design every shift. We dedicate years to tweaking polymer content and microstructure, adapting to the evolving requirements of tire compounders, hose manufacturers, and sole fabricators. Direct experience has taught us that what looks good in laboratory glass sometimes fails on the shop floor—real feedback from processors and OEM customers shapes our selections of recipe, filtration, and packaging.

    Grades, Models, and the People Who Use Them

    We produce Polybutadiene Rubber in several grades, but most inquiries focus on high-cis and low-cis forms. Some plants still ask for medium-vinyl content for specific roll coverings or impact modification tasks, but in practice, high-cis PBR (polybutadiene rubber) is the true workhorse. High-cis content, running above 96%, brings the best combination of resilience and low heat buildup—years working side by side with tire mix lines have shown us that improvement in this direction translates to longer tread life and lower rolling resistance. Truck tire manufacturers want every kilogram to deliver consistent green strength for calendaring and extrusion, so polymer uniformity and dirt level tolerance matter as much as specification sheets suggest.

    Our BR9000 series, for example, has been running in car and truck tires worldwide. This is not just a name—by managing reactor temperature drift, initiator mixes, and solvent purities, we avoid the cold-flow issues that complicate automated rubber handling. Skiving and milling lines count on regular Mooney viscosity, with BR9000 sitting between 44 to 52 for practical mastication. Manufacturers working downstream in golf ball cores, conveyor belts, and automotive bushings also choose low-vinyl grades, but often seek specific molecular weight distribution for their applications. For applications needing extra flexibility at low temperatures, we manufacture BR7020, which uses a nickel-based catalyst and offers a colder glass transition point.

    Facing the Real Needs of Converters and End-users

    We have watched our customers fight to squeeze more use out of raw materials each year. Polybutadiene Rubber stands out in processes demanding bounce, wear resistance, and easy compounding with fillers. Mixing operators always want cleaner mixes and fewer stock handle issues. High-cis BR aids these shops by improving abrasion resistance—meaning fewer batch rejects and more stable throughput over time. Our best evidence comes from trial mixes in their factories, not just our own quality control lab: rubber compounders consistently report improved filler dispersion and lower mixing energy. End-users, especially in large-volume tire manufacturing, report fewer problems with edge cracking and “chunking” in rubber parts, proving that BR’s flexibility carries through to real-world road tests.

    Plastic and ABS producers find a different set of advantages. Polybutadiene Rubber, in its emulsion grades, serves as a toughening agent in plastic blends. Even small changes to molecular structure can affect how well these blends absorb impact force. We have seen this firsthand in collaborations with appliance shell molders and automotive fascia suppliers, who push for a precise balance between impact strength and processability. Our blending line staff must monitor micro-gel content and moisture closely, or else downstream companies report visible defects, something we are always fighting to eliminate.

    Direct Comparisons: Polybutadiene Rubber and Its Alternatives

    We often get asked what sets Polybutadiene apart from SBR, NR, and other synthetic elastomers. It comes down to three points we talk about with compounders: resilience, rolling resistance, and processing behavior. SBR offers better aging and oil resistance, yes, but Polybutadiene absorbs energy in a different way. Resilience measurements on our finished briquettes consistently show rebound values that take the lead, with BR compounds delivering higher elasticity amid repeated deformations. In tire treads and sidewalls, this translates into lower heat buildup. Drivers may not read technical journals, but they feel the smoother ride in long-haul trucks or family sedans built with proper PBR mixes.

    Natural Rubber (NR) wins when it comes to tack and certain mechanical properties, but it suffers in consistency during seasonal plant variations and lacks some cold flexibility. Polybutadiene’s predictable performance, stemming from petrochemical feedstock and reactor control, becomes essential for global brands who cannot afford sudden shifts in end-product quality. While natural rubber is subject to disease outbreaks and regional disruptions, synthetic routes for PBR keep factories supplied through price swings or geopolitical disruptions.

    Comparisons with NBR, EPDM, or other rubbers often center on chemical resistance and weatherability. For applications needing ozone resistance, like automotive seals or outdoor cable insulation, those materials win. Polybutadiene covers the ground of dynamic performance, impact resistance in plastics, and fatigue life in flexed parts. The lines at our blending and finishing units face different cleaning, packaging, and handling challenges based on the polymer. For PBR, keeping storage areas dry and minimizing extrusion die fouling are two of the biggest site-level priorities.

    Production Experience Shapes the Product

    Polymer production is rarely about theory—on every shift, production managers battle column fouling, initiator loading errors, and off-spec batches. It takes years to develop the intuition for when reaction time needs adjustment due to subtle monomer grade changes or impure solvent. Our process team works inside steam and solvent atmospheres, monitoring color, viscosity, gel levels, and even odor on cut slabs. Over the last decade, we invested heavily in filtra­tion upgrades. The payoff came not just in lab results, but in feedback from large-volume tire manufacturers who noticed fewer defects, longer machine cleaning intervals, and a drop in compounding complaints.

    Packaging lines shift formats based on customer needs—block, bale, and crumb forms each need different downstream handling. Compounders who run continuous lines in hot, humid plants prefer certain anti-tack agents, as even small lapses in additive coverage lead to time-consuming cleanup. The flexibility to repackage and relabel to exact shipping requirements comes out of hands-on adjustments by crew members who know exactly how finished PBR reacts to time, temperature, and handling stress. Our close tracking of customer return rates and field complaints gives us early warning of any packaging or product trend—the sort of practical feedback written specifications do not often reveal.

    Allocating Raw Materials: Challenges in a Shifting Landscape

    Raw material access makes each month in production a lesson in logistics and adaptation. Butadiene monomer prices climb with every refinery shutdown or feedstock change, and each spike requires us to juggle plant schedules and order allocation. We maintain direct supply relationships with upstream cracker operations whenever possible, shortening the chain and reducing unexpected purity deviations. Years of running reactor trials with alternate monomer sources give us confidence when faced with tight months—we troubleshoot problems in our own reactors rather than pass along production headaches to downstream users.

    Sustainability pressure grows every year, adding new tasks to already complex supply deals. Customers ask us more often about bio-based sources, or blending recycled content. Our teams have piloted partial bio-butadiene blends, and the early results look promising for certain non-critical applications. Meeting both performance and cost expectations still takes more R&D, but it is already clear which applications can use these grades without loss of rebound or fatigue resistance. Telling the truth about these programs—where performance holds, where it has not reached parity with fossil-based BR—keeps our end-users in the loop and avoids wasted effort on both sides.

    Meeting Industry Standards: More Than a Check Box

    We run extensive testing for every batch—not as a paperwork requirement, but because running off spec means our own customers receive headaches instead of value. Standard ASTM and ISO test protocols guide our lab staff, but no real production batch ever comes out perfectly on every number. Instead, we monitor rolling trends, watching Mooney viscosity, ash content, gel level, and micro-impurities. Polymerization curves in our control rooms tell us how the reaction is behaving, sometimes requiring partial reruns or specialty filtration to avoid bad batches leaving the gate.

    We know that one failed batch in a tire plant can tie up hundreds of thousands in lost product or machine downtime. This direct consequence weighs on every operator and lab tech in the plant. Our incentive program rewards not just perfect numbers, but fast reporting and root-cause analysis. Practical know-how keeps countless tons of Polybutadiene Rubber in specification every year, despite temperature swings, monomer variability, and rotating shifts.

    Troubleshooting Polymer Problems in the Field

    No two customers run polymers the same way, and complaints surface that never appeared in lab formulations. We have made service calls to tire plants miles from the city, watching as local humidity or mixer wear introduces variables we never saw in the plant. Sometimes a batch that tests perfectly in our lab reacts to a new curative package with unexpected softening or premature aging. Close contact with end-users, willingness to review third-party compounding data, and adapting packaging or stabilization practices come directly from our on-site experience.

    It is common to face questions about odor, color, or minor surface defects. Some of these stem from interaction between PBR and local filler choices; others come from storage practices outside our control. Field techs trained inside our own plant lead troubleshooting trips because they have seen those issues resolved on plant lines and know the most common root causes—a different understanding than what a distributor or reseller could provide. This feedback cycle keeps us grounded and improves not just product quality, but shipping, labeling, and even technical documentation.

    Best Practices: Handling, Blending, and Long-Term Use

    Processing Polybutadiene Rubber means staying organized from dock to mixer. Storage in dry, shaded spaces is essential, but avoiding stacking pressure and mechanical deformation is another lesson our warehouse staff learned through experience. We maintain clear guidelines for handling anti-tack surfaces, cleaning bale cages, and transitioning between product lots, knowing that every mistake here ends up as lost material or customer complaints.

    On the compounding floor, we run workshops for longtime partners, sharing tips to alter filler ratios, adjust oil extension, and tune the accelerator system. Lab testing only covers so much—real throughput gains come from shop-floor tweaks learned over decades. We see the greatest ongoing gains in mixing energy reduction, filler uptake speed, and final product appearance. Partnering with molders, extruders, and other rubber processors, we document how slight changes to cure system or plasticizer choice impact every downstream step, trading technical advice based on shared experience, not abstract theory.

    Environmental and Regulatory Concerns: Walking the Talk

    Every producer now faces expanded oversight—air and water emissions, as well as process residue controls. Our chemical engineering teams overhaul scrubbers and solvent recovery units as rules tighten, staying ahead of local and continental regulations. Beyond what gets written into law, we monitor fugitive emissions, train operators for spill response, and conduct regular audits based on where most incidents have emerged in the past. This discipline pays off, as violations not only cost money but damage relationships with buyers under the microscope for green procurement.

    Waste cutting extends beyond emission control. Efficient process design, reuse of process residues, and careful filtration cut down what gets sent to disposal. We invest in carbon recovery and solvent recycling, not because of regulatory threats, but because every kilogram saved turns up as cost savings and operational resilience during upsets.

    Looking Forward: Innovation Rooted in Daily Practice

    Change in our industry always comes from field experience first. Over the years, we have seen process improvements that short-circuit old batch cooling schemes, raise monomer conversion rates, or adapt the formulation to new green tire requirements. Our technical teams run side-by-side with plant operators and end-user compounders, recognizing that good ideas come up at 3 a.m. while fixing a plugged die, not just during morning meetings.

    Recent advances in bio-based raw materials, digital reactor controls, and online product tracing would mean little without the hands-on expertise of each crew member on the plant floor. Polymer design gets driven by the reality of customer complaints, process bottlenecks, and raw material tightness. We keep lines open with major users, smaller processors, and material scientists, knowing that future grades of Polybutadiene Rubber will not just match paperwork values, but outperform in mixes throughout the chemical, plastic, and tire supply chains.

    Conclusion: Why We Still Believe in Polybutadiene Rubber

    Years of direct factory work have taught us Polybutadiene Rubber earns its place with rubber processors, tire manufacturers, and plastic blenders because of real performance, high flexibility, and the ability to adapt to changing demands. Our choices on grade, catalyst, stabilization, and packaging have always come from lived experience, not remote marketing ideas. The challenges ahead—raw material scarcity, sustainability demands, and evolving tire standards—push us to learn, adapt, and improve every year. With each production cycle, we see how Polybutadiene Rubber remains a practical, resilient choice for industries that demand more from every material entering their line.